01 - Set oven to 400°F (200°C) for optimal baking temperature.
02 - Dry chicken breasts thoroughly with paper towels, then season all sides with salt, black pepper, and garlic powder.
03 - In a shallow bowl, mix grated Parmesan cheese, fine breadcrumbs, chopped parsley, and dried oregano. Coat each chicken breast evenly with the crust mixture, pressing gently for adherence.
04 - Heat 2 tablespoons olive oil in a large ovenproof skillet over medium-high heat. Place crusted chicken breasts in skillet and sear for 2 to 3 minutes per side until golden brown.
05 - Transfer skillet with chicken to the preheated oven. Bake for 18 to 22 minutes, or until internal temperature reaches 165°F (74°C) and juices run clear.
06 - While chicken bakes, combine roasted red bell peppers, garlic, 2 tablespoons olive oil, balsamic vinegar, smoked paprika, and salt and pepper to taste in a blender or food processor. Blend until smooth.
07 - Taste the sauce, adjust seasoning as needed with additional salt or pepper, and gently heat in a small saucepan over low heat if warmer sauce is preferred.
08 - Arrange baked Parmesan-crusted chicken breasts on serving plates. Spoon the warm roasted red pepper sauce over the top and garnish with extra parsley if desired.